Ferocen - Revision history

Masa andoljsek at 15:54, 7 January 2023

2023-01-07T15:54:21Z

← Older revision		Revision as of 15:54, 7 January 2023
Line 126:		Line 126:
	Zaradi enostavne substitucije je bilo pripravljenih veliko derivatov ferocena z neobičajno strukturo. Na primer penta(ferocenil)ciklopentadienilni ligand <sup>[79]</sup> vsebuje ciklopentadienilni anion, derivatiziran s petimi ferocenskimi substituenti.		Zaradi enostavne substitucije je bilo pripravljenih veliko derivatov ferocena z neobičajno strukturo. Na primer penta(ferocenil)ciklopentadienilni ligand <sup>[79]</sup> vsebuje ciklopentadienilni anion, derivatiziran s petimi ferocenskimi substituenti.

	V '''heksaferocenilbenzenu''', C<sub>6</sub>(η<sub>5</sub>-C<sub>5</sub>H<sub>4</sub>)Fe(η<sub>5</sub>-C<sub>5</sub>H<sub>5</sub>)]<sub>6</sub>, ima vseh šest položajev na molekuli benzena ferocenilne substituente (R).<sup>[80]</sup> Rentgenska difrakcijska analiza te spojine potrjuje, da ciklopentadienilni ligandi niso koplanarni z benzenskim jedrom, ampak imajo izmenične diedrske kote +30° in −80°. Zaradi sterične oviranosti so ferocenili rahlo upognjeni s koti 177° in imajo podaljšane C-Fe vezi. Kvarterni ciklopentadienilni ogljikovi atomi so prav tako piramidalizirani. Poleg tega ima benzenovo jedro konformacijo stola z diedričnimi koti 14° in prikazuje spreminjanje dolžine vezi med 142,7 pm in 141,1 pm, kar kaže na sterično oviranost substituentov.		V '''heksaferocenilbenzenu''', C<sub>6</sub>(η<sub>5</sub>-C<sub>5</sub>H<sub>4</sub>)Fe(η<sub>5</sub>-C<sub>5</sub>H<sub>5</sub>)<sub>6</sub>, ima vseh šest položajev na molekuli benzena ferocenilne substituente (R).<sup>[80]</sup> Rentgenska difrakcijska analiza te spojine potrjuje, da ciklopentadienilni ligandi niso koplanarni z benzenskim jedrom, ampak imajo izmenične diedrske kote +30° in −80°. Zaradi sterične oviranosti so ferocenili rahlo upognjeni s koti 177° in imajo podaljšane C-Fe vezi. Kvarterni ciklopentadienilni ogljikovi atomi so prav tako piramidalizirani. Poleg tega ima benzenovo jedro konformacijo stola z diedričnimi koti 14° in prikazuje spreminjanje dolžine vezi med 142,7 pm in 141,1 pm, kar kaže na sterično oviranost substituentov.

	Objavljena je bila sinteza heksaferocenilbenzena z uporabo Negishijeve sklopitve heksajodidobenzena in diferocenilcinka z uporabo tris(dibenzilidenaceton)dipaladija(0) kot katalizatorja v tetrahidrofuranu: <sup>[80]</sup>		Objavljena je bila sinteza heksaferocenilbenzena z uporabo Negishijeve sklopitve heksajodidobenzena in diferocenilcinka z uporabo tris(dibenzilidenaceton)dipaladija(0) kot katalizatorja v tetrahidrofuranu: <sup>[80]</sup>

Masa andoljsek at 15:51, 7 January 2023

2023-01-07T15:51:47Z

Show changes

Masa andoljsek at 13:59, 7 January 2023

2023-01-07T13:59:34Z

← Older revision		Revision as of 13:59, 7 January 2023
Line 307:		Line 307:

	84. ^ Elbert J, Gallei M, Rüttiger C, Brunsen A, Didzoleit H, Stühn B, Rehahn M (2013). "Ferrocene Polymers for Switchable Surface Wettability". ''[https://en.wikipedia.org/wiki/Organometallics Organometallics.]'' '''32''' (20): 5873–5878. doi:10.1021/om400468p.		84. ^ Elbert J, Gallei M, Rüttiger C, Brunsen A, Didzoleit H, Stühn B, Rehahn M (2013). "Ferrocene Polymers for Switchable Surface Wettability". ''[https://en.wikipedia.org/wiki/Organometallics Organometallics.]'' '''32''' (20): 5873–5878. doi:10.1021/om400468p.

			73. ^ [chrome-extension://efaidnbmnnnibpcajpcglclefindmkaj/https://patentimages.storage.googleapis.com/dd/6e/d6/9fd8e3c5c96b67/US9738673.pdf US 9738673], Yong J, Lu C, "Ferrocene Derivative, Preparation Method and Use Thereof.", issued August 22, 2017, assigned to Xiamen Institute of Rare Earth Materials.

			74. ^ <sup>a b </sup> Top S, Vessières A, Leclercq G, Quivy J, Tang J, Vaissermann J, et al. (November 2003). "Synthesis, biochemical properties and molecular modelling studies of organometallic specific estrogen receptor modulators (SERMs), the ferrocifens and hydroxyferrocifens: evidence for an antiproliferative effect of hydroxyferrocifens on both hormone-dependent and hormone-independent breast cancer cell lines". ''Chemistry.'' '''9''' (21): 5223–5236. [https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.200305024 doi:10.1002/chem.200305024.] [https://en.wikipedia.org/wiki/PubMed#PubMed_identifier PMID] [https://pubmed.ncbi.nlm.nih.gov/14613131/ 14613131.]

			75. ^ Dagani R (16 September 2002). [http://pubsapp.acs.org/cen/science/8037/8037sci1.html? "The Bio Side of Organometallics".] ''[https://en.wikipedia.org/wiki/Chemical_%26_Engineering_News Chemical and Engineering News.]'' '''80''' (37): 23–29. doi:10.1021/cen-v080n037.p023.

			76. ^ [https://www.rocketmotorparts.com/index.aspx?pageid=1577809&prodid=15759228 "Ferrocene Burn Rate Catalyst".] ''www.rocketmotorparts.com''. Retrieved 2020-01-13.

			77. ^ Zakrzewski J, Giannotti C (1990). "An improved photochemical synthesis of azaferrocene". ''J. Organomet. Chem.'' '''388''' (1–2): 175–179. [https://www.sciencedirect.com/science/article/abs/pii/0022328X90853597?via%3Dihub doi:10.1016/0022-328X(90)85359-7.]

			78. ^ Efraty A, Jubran N, Goldman A (1982). "Chemistry of some η5-pyrrolyl- and η1-N-pyrrolyliron complexes". ''Inorg. Chem.'' '''21''' (3): 868–873. [https://pubs.acs.org/doi/abs/10.1021/ic00133a006 doi:10.1021/ic00133a006.]

			79. ^ Yu Y, Bond AD, Leonard PW, Vollhardt KP, Whitener GD (March 2006). "Syntheses, structures, and reactivity of radial oligocyclopentadienyl metal complexes: penta(ferrocenyl)cyclopentadienyl and congeners". ''Angewandte Chemie.'' '''45''' (11): 1794–1799. [https://onlinelibrary.wiley.com/doi/10.1002/anie.200504047 doi:10.1002/anie.200504047.] [https://en.wikipedia.org/wiki/PubMed#PubMed_identifier PMID] [https://pubmed.ncbi.nlm.nih.gov/16470902/ 16470902.]

			80. ^ <sup>a b </sup> Yu Y, Bond AD, Leonard PW, Lorenz UJ, Timofeeva TV, Vollhardt KP, et al. (June 2006). [ https://zenodo.org/record/896672#.Y7l5EHbMKUk "Hexaferrocenylbenzene".] ''Chemical Communications'' (24): 2572–2574. [https://pubs.rsc.org/en/content/articlelanding/2006/CC/b604844g doi:10.1039/b604844g.] [https://en.wikipedia.org/wiki/PubMed#PubMed_identifier PMID] [https://pubmed.ncbi.nlm.nih.gov/16779481/ 16779481.]

			81. ^ <sup>a b c</sup> Pietschnig R (October 2016). [https://pubs.rsc.org/en/content/articlelanding/2016/CS/C6CS00196C "Polymers with pendant ferrocenes".] ''Chemical Society Reviews.'' '''45''' (19): 5216–5231. [https://pubs.rsc.org/en/content/articlelanding/2016/CS/C6CS00196C doi:10.1039/C6CS00196C.] [https://en.wikipedia.org/wiki/PubMed#PubMed_identifier PMID] [https://pubmed.ncbi.nlm.nih.gov/16779481/ 27156979.]

			82. ^ Conroy D, Moisala A, Cardoso S, Windle A, Davidson J (2010). "Carbon nanotube reactor: Ferrocene decomposition, iron particle growth, nanotube aggregation and scale-up". ''[https://en.wikipedia.org/wiki/Chemical_Engineering_Science Chem. Eng. Sci.]'' '''65''' (10): 2965–2977. [https://www.sciencedirect.com/science/article/pii/S0009250910000369?via%3Dihub doi:10.1016/j.ces.2010.01.019.]

			83. ^ Liu WY, Xu QH, Ma YX, Liang YM, Dong NL, Guan DP (2001). "Solvent-free synthesis of ferrocenylethene derivatives". ''[https://en.wikipedia.org/wiki/Journal_of_Organometallic_Chemistry J. Organomet. Chem.]'' '''625''': 128–132. [https://www.sciencedirect.com/science/article/abs/pii/S0022328X0000927X?via%3Dihub doi: 10.1016/S0022-328X(00)00927-X.]

			84. ^ Elbert J, Gallei M, Rüttiger C, Brunsen A, Didzoleit H, Stühn B, Rehahn M (2013). "Ferrocene Polymers for Switchable Surface Wettability". ''[https://en.wikipedia.org/wiki/Organometallics Organometallics.]'' '''32''' (20): 5873–5878. [https://pubs.acs.org/doi/10.1021/om400468p doi:10.1021/om400468p.]

Masa andoljsek at 13:46, 7 January 2023

2023-01-07T13:46:21Z

← Older revision		Revision as of 13:46, 7 January 2023
Line 306:		Line 306:
	83. ^ Liu WY, Xu QH, Ma YX, Liang YM, Dong NL, Guan DP (2001). "Solvent-free synthesis of ferrocenylethene derivatives". ''J. Organomet. Chem.'' '''625''': 128–132. doi:10.1016/S0022-328X(00)00927-X.		83. ^ Liu WY, Xu QH, Ma YX, Liang YM, Dong NL, Guan DP (2001). "Solvent-free synthesis of ferrocenylethene derivatives". ''J. Organomet. Chem.'' '''625''': 128–132. doi:10.1016/S0022-328X(00)00927-X.

	84. ^ Elbert J, Gallei M, Rüttiger C, Brunsen A, Didzoleit H, Stühn B, Rehahn M (2013). "Ferrocene Polymers for Switchable Surface Wettability". ''~~Organometallics.'' '''32''' (20): 5873–5878. doi:10.1021/om400468p.~~		84. ^ Elbert J, Gallei M, Rüttiger C, Brunsen A, Didzoleit H, Stühn B, Rehahn M (2013). "Ferrocene Polymers for Switchable Surface Wettability". ''[https://en.wikipedia.org/wiki/Organometallics Organometallics.]'' '''32''' (20): 5873–5878. doi:10.1021/om400468p.

	~~3. ^ "FERROCENE Material safety data sheet". ''ChemSrc.''~~

	~~1. ^~~ [https://en.wikipedia.org/wiki/~~International_Union_of_Pure_and_Applied_Chemistry International Union of Pure and Applied Chemistry (2014)~~.]. ''~~Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013~~''~~. The Royal Society of Chemistry.The Royal Society of Chemistry. p. 1041~~. doi:10.~~1039~~/~~9781849733069. ISBN 978-0-85404-182-4~~.

Masa andoljsek at 13:37, 7 January 2023

2023-01-07T13:37:19Z

← Older revision		Revision as of 13:37, 7 January 2023
Line 310:		Line 310:
	3. ^ "FERROCENE Material safety data sheet". ''ChemSrc.''		3. ^ "FERROCENE Material safety data sheet". ''ChemSrc.''

	1. ^ [https://en.wikipedia.org/wiki/International_Union_of_Pure_and_Applied_Chemistry]. ''Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013''. The Royal Society of Chemistry.The Royal Society of Chemistry. p. 1041. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.		1. ^ [https://en.wikipedia.org/wiki/International_Union_of_Pure_and_Applied_Chemistry International Union of Pure and Applied Chemistry (2014).]. ''Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013''. The Royal Society of Chemistry.The Royal Society of Chemistry. p. 1041. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.

Masa andoljsek at 13:35, 7 January 2023

2023-01-07T13:35:52Z

← Older revision		Revision as of 13:35, 7 January 2023
Line 307:		Line 307:

	84. ^ Elbert J, Gallei M, Rüttiger C, Brunsen A, Didzoleit H, Stühn B, Rehahn M (2013). "Ferrocene Polymers for Switchable Surface Wettability". ''Organometallics.'' '''32''' (20): 5873–5878. doi:10.1021/om400468p.		84. ^ Elbert J, Gallei M, Rüttiger C, Brunsen A, Didzoleit H, Stühn B, Rehahn M (2013). "Ferrocene Polymers for Switchable Surface Wettability". ''Organometallics.'' '''32''' (20): 5873–5878. doi:10.1021/om400468p.

			3. ^ "FERROCENE Material safety data sheet". ''ChemSrc.''

			1. ^ [https://en.wikipedia.org/wiki/International_Union_of_Pure_and_Applied_Chemistry]. ''Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013''. The Royal Society of Chemistry.The Royal Society of Chemistry. p. 1041. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.

Masa andoljsek at 13:30, 7 January 2023

2023-01-07T13:30:13Z

← Older revision		Revision as of 13:30, 7 January 2023
Line 138:		Line 138:

	==Sklici==		==Sklici==
	1. ^ International Union of Pure and Applied Chemistry (2014). ''Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013''. The Royal Society of Chemistry.The Royal Society of Chemistry. p. 1041. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.		1. ^ International Union of Pure and Applied Chemistry (2014). (https://en.wikipedia.org/wiki/International_Union_of_Pure_and_Applied_Chemistry) ''Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013''. The Royal Society of Chemistry.The Royal Society of Chemistry. p. 1041. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.

	2. ^ "Ferrocene (102-54-5)". ''ChemicalBook.'' Retrieved 3 February 2010.		2. ^ "Ferrocene (102-54-5)". ''ChemicalBook.'' Retrieved 3 February 2010.

Masa andoljsek at 13:29, 7 January 2023

2023-01-07T13:29:12Z

← Older revision		Revision as of 13:29, 7 January 2023
Line 1:		Line 1:
			''Povzeto po '''Ferrocene''' from Wikipedia, the free encyclopedia:'' https://en.wikipedia.org/wiki/Ferrocene

	'''Ferocen''' je organokovinska spojina s formulo Fe(C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>. Struktura molekule je kompleks, ki je sestavljen iz dveh ciklopentadienilnih obročev vezanih na centralni železov atom. Spojina je oranžna trdna snov, ki ima vonj po kafri. Spojina sublimira nad sobno temperaturo in se topi v večini organskih topil. Spojina je znana po njeni izjemni stabilnosti. Ni občutljiva na vodo, zrak, močne baze, in je termično stabilna do 400 °C, brez razpada kompleksa. V oksidativnih pogojih lahko reverzibilno reagira z močnimi kislinami, da tvori ferocenijev kation Fe(C<sub>5</sub>H<sub>5</sub>)<sup>+</sup><sub>2</sub>.<sup>[8]</sup>		'''Ferocen''' je organokovinska spojina s formulo Fe(C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>. Struktura molekule je kompleks, ki je sestavljen iz dveh ciklopentadienilnih obročev vezanih na centralni železov atom. Spojina je oranžna trdna snov, ki ima vonj po kafri. Spojina sublimira nad sobno temperaturo in se topi v večini organskih topil. Spojina je znana po njeni izjemni stabilnosti. Ni občutljiva na vodo, zrak, močne baze, in je termično stabilna do 400 °C, brez razpada kompleksa. V oksidativnih pogojih lahko reverzibilno reagira z močnimi kislinami, da tvori ferocenijev kation Fe(C<sub>5</sub>H<sub>5</sub>)<sup>+</sup><sub>2</sub>.<sup>[8]</sup>
	Odkritju ferocena pogosto pripisujejo zasluge za hiter razvoj organokovinske kemije.		Odkritju ferocena pogosto pripisujejo zasluge za hiter razvoj organokovinske kemije.

Masa andoljsek at 13:26, 7 January 2023

2023-01-07T13:26:59Z

Masa andoljsek at 13:24, 7 January 2023

2023-01-07T13:24:30Z

← Older revision		Revision as of 13:24, 7 January 2023
Line 136:		Line 136:

	==Sklici==		==Sklici==
	1. International Union of Pure and Applied Chemistry (2014). ''Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013''. The Royal Society of Chemistry.The Royal Society of Chemistry. p. 1041. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.		1. ^ International Union of Pure and Applied Chemistry (2014). ''Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013''. The Royal Society of Chemistry.The Royal Society of Chemistry. p. 1041. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.

	2. ^ "Ferrocene (102-54-5)". ''ChemicalBook.'' Retrieved 3 February 2010.		2. ^ "Ferrocene (102-54-5)". ''ChemicalBook.'' Retrieved 3 February 2010.
Line 146:		Line 146:
	5. ^ Mohammadi N, Ganesan A, Chantler CT, Wang F (2012). "Differentiation of ferrocene D5d and D5h conformers using IR spectroscopy". ''Journal of Organometallic Chemistry.'' '''713''': 51–59. doi:10.1016/j.jorganchem.2012.04.009.		5. ^ Mohammadi N, Ganesan A, Chantler CT, Wang F (2012). "Differentiation of ferrocene D5d and D5h conformers using IR spectroscopy". ''Journal of Organometallic Chemistry.'' '''713''': 51–59. doi:10.1016/j.jorganchem.2012.04.009.

	6. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0205". National Institute for Occupational Safety and Health (NIOSH).		6. ^ <sup>a b c</sup> NIOSH Pocket Guide to Chemical Hazards. "#0205". National Institute for Occupational Safety and Health (NIOSH).

	7. ^ "Ferrocene MSDS". ''ScienceLab.'' Archived from the original on 2015-12-12. Retrieved 2015-11-25.		7. ^ "Ferrocene MSDS". ''ScienceLab.'' Archived from the original on 2015-12-12. Retrieved 2015-11-25.

← Older revision		Revision as of 13:26, 7 January 2023
Line 150:		Line 150:
	7. ^ "Ferrocene MSDS". ''ScienceLab.'' Archived from the original on 2015-12-12. Retrieved 2015-11-25.		7. ^ "Ferrocene MSDS". ''ScienceLab.'' Archived from the original on 2015-12-12. Retrieved 2015-11-25.

	8. ^ a b c d e Werner H (June 2012). "At least 60 years of ferrocene: the discovery and rediscovery of the sandwich complexes". ''Angewandte Chemie.'' '''51''' (25): 6052–6058. doi:10.1002/anie.201201598. PMID 22573490.		8. ^ <sup>a b c d e</sup> Werner H (June 2012). "At least 60 years of ferrocene: the discovery and rediscovery of the sandwich complexes". ''Angewandte Chemie.'' '''51''' (25): 6052–6058. doi:10.1002/anie.201201598. PMID 22573490.

	9. ^ a b c d Pauson PL (2001). "Ferrocene—how it all began". ''Journal of Organometallic Chemistry.'' 637–639: 3–6. doi:10.1016/S0022-328X(01)01126-3.		9. ^ <sup>a b c d</sup> Pauson PL (2001). "Ferrocene—how it all began". ''Journal of Organometallic Chemistry.'' 637–639: 3–6. doi:10.1016/S0022-328X(01)01126-3.

	10. ^ a b c Miller SA, Tebboth JA, Tremaine JF (1952). "114. Dicyclopentadienyliron". ''J. Chem. Soc.'': 632–635. doi:10.1039/JR9520000632.		10. ^ <sup>a b c</sup> Miller SA, Tebboth JA, Tremaine JF (1952). "114. Dicyclopentadienyliron". ''J. Chem. Soc.'': 632–635. doi:10.1039/JR9520000632.

	11. ^ a b c Laszlo P, Hoffmann R (January 2000). "Ferrocene: Ironclad History or Rashomon Tale?". ''Angewandte Chemie.'' '''39''' (1): 123–124. doi:10.1002/(SICI)1521-3773(20000103)39:1<123::AID-ANIE123>3.0.CO;2-Z. PMID 10649350.		11. ^ <sup>a b c</sup> Laszlo P, Hoffmann R (January 2000). "Ferrocene: Ironclad History or Rashomon Tale?". ''Angewandte Chemie.'' '''39''' (1): 123–124. doi:10.1002/(SICI)1521-3773(20000103)39:1<123::AID-ANIE123>3.0.CO;2-Z. PMID 10649350.

	12. ^ a b c Kealy TJ, Pauson PL (1951). "A New Type of Organo-Iron Compound". ''Nature.'' '''168''' (4285): 1039–1040. Bibcode:1951Natur.168.1039K. doi:10.1038/1681039b0. S2CID 4181383.		12. ^ <sup>a b c</sup> Kealy TJ, Pauson PL (1951). "A New Type of Organo-Iron Compound". ''Nature.'' '''168''' (4285): 1039–1040. Bibcode:1951Natur.168.1039K. doi:10.1038/1681039b0. S2CID 4181383.

	13.^ Federman Neto A, Pelegrino AC, Darin VA (2004). "Ferrocene: 50 Years of Transition Metal Organometallic Chemistry — From Organic and Inorganic to Supramolecular Chemistry (Abstract)".		13.^ Federman Neto A, Pelegrino AC, Darin VA (2004). "Ferrocene: 50 Years of Transition Metal Organometallic Chemistry — From Organic and Inorganic to Supramolecular Chemistry (Abstract)".
Line 173:		Line 173:
	18. ^ Okuda J (2016-12-28). "Ferrocene - 65 Years After". ''European Journal of Inorganic Chemistry.'' '''2017''' (2): 217–219. doi:10.1002/ejic.201601323. ISSN 1434-1948.		18. ^ Okuda J (2016-12-28). "Ferrocene - 65 Years After". ''European Journal of Inorganic Chemistry.'' '''2017''' (2): 217–219. doi:10.1002/ejic.201601323. ISSN 1434-1948.

	19. ^ a b Eiland PF, Pepinsky R (1952). "X-ray Examination of Iron Biscyclopentadienyl". ''J. Am. Chem. Soc.'' '''74''' (19): 4971. doi:10.1021/ja01139a527.		19. ^ <sup>a b </sup> Eiland PF, Pepinsky R (1952). "X-ray Examination of Iron Biscyclopentadienyl". ''J. Am. Chem. Soc.'' '''74''' (19): 4971. doi:10.1021/ja01139a527.

	20. ^ Dunitz JD, Orgel LE (1953). "Bis-Cyclopentadienyl – A Molecular Sandwich". ''Nature.'' '''171''' (4342): 121–122. Bibcode:1953Natur.171..121D. doi:10.1038/171121a0. S2CID 4263761.		20. ^ Dunitz JD, Orgel LE (1953). "Bis-Cyclopentadienyl – A Molecular Sandwich". ''Nature.'' '''171''' (4342): 121–122. Bibcode:1953Natur.171..121D. doi:10.1038/171121a0. S2CID 4263761.
Line 208:		Line 208:
	35. ^ Wilkinson G, Cotton FA (1959). "Cyclopentadienyl and Arene Metal Compounds". ''Progress in Inorganic Chemistry.'' Vol. 1. pp. 1–124. doi:10.1002/9780470166024.ch1. ISBN 978-0-470-16602-4.		35. ^ Wilkinson G, Cotton FA (1959). "Cyclopentadienyl and Arene Metal Compounds". ''Progress in Inorganic Chemistry.'' Vol. 1. pp. 1–124. doi:10.1002/9780470166024.ch1. ISBN 978-0-470-16602-4.

	36. ^ a b Wilkinson G (1956). "Ferrocene". ''Organic Syntheses.'' '''36''' 31. doi:10.15227/orgsyn.036.0031.		36. ^ <sup>a b </sup> Wilkinson G (1956). "Ferrocene". ''Organic Syntheses.'' '''36''' 31. doi:10.15227/orgsyn.036.0031.

	37. ^ Jolly WL (1970). ''The Synthesis and Characterization of Inorganic Compounds.'' New Jersey: Prentice-Hall. ISBN 9780138799328.		37. ^ Jolly WL (1970). ''The Synthesis and Characterization of Inorganic Compounds.'' New Jersey: Prentice-Hall. ISBN 9780138799328.
Line 250:		Line 250:
	56. ^ Atkinson RC, Gibson VC, Long NJ (June 2004). "The syntheses and catalytic applications of unsymmetrical ferrocene ligands". ''Chemical Society Reviews.'' '''33''' (5): 313–328. doi:10.1039/B316819K. PMID 15272371.		56. ^ Atkinson RC, Gibson VC, Long NJ (June 2004). "The syntheses and catalytic applications of unsymmetrical ferrocene ligands". ''Chemical Society Reviews.'' '''33''' (5): 313–328. doi:10.1039/B316819K. PMID 15272371.

	57. ^ a b Blaser HU (2002). "Solvias Josiphos ligands: From discovery to technical applications". ''Topics in Catalysis.'' '''19''': 3–16. doi:10.1023/a:1013832630565. S2CID 95738043.		57. ^ <sup>a b </sup> Blaser HU (2002). "Solvias Josiphos ligands: From discovery to technical applications". ''Topics in Catalysis.'' '''19''': 3–16. doi:10.1023/a:1013832630565. S2CID 95738043.

	58. ^ Zhou QL (2011). ''Privileged Chiral Ligands and Catalysts.'' Weinheim: Wiley-VCH Verlag. ISBN 978-3-527-63521-4.		58. ^ Zhou QL (2011). ''Privileged Chiral Ligands and Catalysts.'' Weinheim: Wiley-VCH Verlag. ISBN 978-3-527-63521-4.

	59. ^ a b Stepnicka P (2008). Ferrocenes: ''Ligands, Materials and Biomolecules.'' Hoboken, NJ: J. Wiley. ISBN 978-0-470-03585-6.		59. ^ <sup>a b </sup> Stepnicka P (2008). Ferrocenes: ''Ligands, Materials and Biomolecules.'' Hoboken, NJ: J. Wiley. ISBN 978-0-470-03585-6.

	60. ^ Bennett J (26 November 2004). ''Application of fuel additives'' (PDF). International Conference on Automotive Technology. Istanbul. Archived from the original (PDF) on 2006-05-05.		60. ^ Bennett J (26 November 2004). ''Application of fuel additives'' (PDF). International Conference on Automotive Technology. Istanbul. Archived from the original (PDF) on 2006-05-05.
Line 284:		Line 284:
	73. ^ US 9738673, Yong J, Lu C, "Ferrocene Derivative, Preparation Method and Use Thereof.", issued August 22, 2017, assigned to Xiamen Institute of Rare Earth Materials.		73. ^ US 9738673, Yong J, Lu C, "Ferrocene Derivative, Preparation Method and Use Thereof.", issued August 22, 2017, assigned to Xiamen Institute of Rare Earth Materials.

	74. ^ a b Top S, Vessières A, Leclercq G, Quivy J, Tang J, Vaissermann J, et al. (November 2003). "Synthesis, biochemical properties and molecular modelling studies of organometallic specific estrogen receptor modulators (SERMs), the ferrocifens and hydroxyferrocifens: evidence for an antiproliferative effect of hydroxyferrocifens on both hormone-dependent and hormone-independent breast cancer cell lines". ''Chemistry.'' '''9''' (21): 5223–5236. doi:10.1002/chem.200305024. PMID 14613131.		74. ^ <sup>a b </sup> Top S, Vessières A, Leclercq G, Quivy J, Tang J, Vaissermann J, et al. (November 2003). "Synthesis, biochemical properties and molecular modelling studies of organometallic specific estrogen receptor modulators (SERMs), the ferrocifens and hydroxyferrocifens: evidence for an antiproliferative effect of hydroxyferrocifens on both hormone-dependent and hormone-independent breast cancer cell lines". ''Chemistry.'' '''9''' (21): 5223–5236. doi:10.1002/chem.200305024. PMID 14613131.

	75. ^ Dagani R (16 September 2002). "The Bio Side of Organometallics". ''Chemical and Engineering News.'' '''80''' (37): 23–29. doi:10.1021/cen-v080n037.p023.		75. ^ Dagani R (16 September 2002). "The Bio Side of Organometallics". ''Chemical and Engineering News.'' '''80''' (37): 23–29. doi:10.1021/cen-v080n037.p023.
Line 296:		Line 296:
	79. ^ Yu Y, Bond AD, Leonard PW, Vollhardt KP, Whitener GD (March 2006). "Syntheses, structures, and reactivity of radial oligocyclopentadienyl metal complexes: penta(ferrocenyl)cyclopentadienyl and congeners". ''Angewandte Chemie.'' '''45''' (11): 1794–1799. doi:10.1002/anie.200504047. PMID 16470902.		79. ^ Yu Y, Bond AD, Leonard PW, Vollhardt KP, Whitener GD (March 2006). "Syntheses, structures, and reactivity of radial oligocyclopentadienyl metal complexes: penta(ferrocenyl)cyclopentadienyl and congeners". ''Angewandte Chemie.'' '''45''' (11): 1794–1799. doi:10.1002/anie.200504047. PMID 16470902.

	80. ^ a b Yu Y, Bond AD, Leonard PW, Lorenz UJ, Timofeeva TV, Vollhardt KP, et al. (June 2006). "Hexaferrocenylbenzene". ''Chemical Communications'' (24): 2572–2574. doi:10.1039/b604844g. PMID 16779481.		80. ^ <sup>a b </sup> Yu Y, Bond AD, Leonard PW, Lorenz UJ, Timofeeva TV, Vollhardt KP, et al. (June 2006). "Hexaferrocenylbenzene". ''Chemical Communications'' (24): 2572–2574. doi:10.1039/b604844g. PMID 16779481.

	81. ^ a b c Pietschnig R (October 2016). "Polymers with pendant ferrocenes". ''Chemical Society Reviews.'' '''45''' (19): 5216–5231. doi:10.1039/C6CS00196C. PMID 27156979.		81. ^ <sup>a b c</sup> Pietschnig R (October 2016). "Polymers with pendant ferrocenes". ''Chemical Society Reviews.'' '''45''' (19): 5216–5231. doi:10.1039/C6CS00196C. PMID 27156979.

	82. ^ Conroy D, Moisala A, Cardoso S, Windle A, Davidson J (2010). "Carbon nanotube reactor: Ferrocene decomposition, iron particle growth, nanotube aggregation and scale-up". ''Chem. Eng. Sci.'' '''65''' (10): 2965–2977. doi:10.1016/j.ces.2010.01.019.		82. ^ Conroy D, Moisala A, Cardoso S, Windle A, Davidson J (2010). "Carbon nanotube reactor: Ferrocene decomposition, iron particle growth, nanotube aggregation and scale-up". ''Chem. Eng. Sci.'' '''65''' (10): 2965–2977. doi:10.1016/j.ces.2010.01.019.